Saturday, 21 September 2019

BASIC BUFFER SOLUTION


Basic Buffer Solution
(Weak base + conjugate acid)
Preparation
By adding a weak base to a salt which contains its conjugate acid.
Example
NH3 and NH4Cl

Reaction
(W.B) : NH3 + H2O   NH4+   + OH-

(C.A):  NH4Cl   NH4+  + Cl-


Henderson-Hasselbalch’s equation

pH = - log Kb  +  log  [ conjugate acid ]
                                    [ weak base ]
Addition of a small amount of strong acid







When a small amount of acid is added (H+),

NH3(aq) +  H+(aq) NH4+(aq)

Acid (H+) form strong acid reacts with NH3to form NH4+.
Acid added is consumed.
Concentration of [NH4+] increase, but concentrations of [NH3] decrease.
As a result, pH of the solution is not much affected.


Addition of a small amount of strong acid


When a small amount of base is added (OH-),

OH-(aq) + NH4+ (aq) NH3 (aq) + H2O(l)

Base (OH-) form strong base reacts with NH4+ to form NH3
Base added is consumed.
Concentration of [NH3] increase, but concentrations of [NH4+] decrease.
As a result, pH of the solution is not much affected.





NOTE: The pH of a buffer solution can always be maintained no matter a strong acid or a strong base is added

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