Basic Buffer Solution
(Weak base + conjugate acid)
|
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Preparation
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By adding a weak base to a
salt which contains its conjugate acid.
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Example
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NH3 and NH4Cl
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Reaction
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(C.A):
NH4Cl → NH4+ + Cl-
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Henderson-Hasselbalch’s equation
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pH = - log Kb +
log [ conjugate acid ]
[
weak base ]
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Addition of a small amount of strong acid
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When a small amount of acid is added (H+),
NH3(aq) + H+(aq)
→NH4+(aq)
Acid (H+) form
strong acid reacts with NH3to
form NH4+.
Acid added is consumed.
Concentration of [NH4+]
increase, but concentrations of [NH3]
decrease.
As a result, pH of the
solution is not much affected.
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Addition of a small amount of strong acid
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When a small amount of base is added (OH-),
OH-(aq) + NH4+
(aq) →NH3 (aq) + H2O(l)
Base (OH-) form
strong base reacts with NH4+
to form NH3
Base added is consumed.
Concentration of [NH3] increase, but
concentrations of [NH4+]
decrease.
As a result, pH of the
solution is not much affected.
|
NOTE: The pH of a buffer solution can always be maintained
no matter a strong acid or a strong base is added
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Saturday, 21 September 2019
BASIC BUFFER SOLUTION
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